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The second law of thermodynamics states that processes occur in a certain direction, not in just any direction. • Physical processes in nature can proceed. The second law of thermodynamics asserts that processes occur in a certain direction and that the energy has quality as well as quantity. STATEMENT OF THE SECOND LAW The second law of thermodynamics states that : whenever a spontaneous process takes place, it is accompanied by an increase in the Chapter 20: Entropy and the Second Law of Thermodynamics. The Conservation of Energy law allows energy to flow bi- directionally between its various forms.Thermodynamics is concerned with the maximum fraction of a quantity of heat that can be converted into work. Page 2. Second Law of Thermodynamics. The First Law